{双（硫氰酸根合-κN）-铜（II）}-N，N-二甲基-N'-[1-（2-吡啶基）亚乙基]丙烷-1，3-二胺
{N,N-Dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]propane-1,3-diamine}bis(thio-cyanato-κN)-copper(II).
作者信息
Xue Ling-Wei, Zhao Gan-Qing, Han Yong-Jun, Chen Li-Hua, Peng Qin-Long
机构信息
College of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan, Henan 467000, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 18;66(Pt 10):m1274. doi: 10.1107/S1600536810036378.
In the title complex, [Cu(NCS)(2)(C(12)H(19)N(3))], the Cu(II) atom is five-coordinated in a square-pyramidal geometry defined by one pyridine N, one imine N, and one amine N atom of the tridentate Schiff base ligand and two N-bonded thio-cyanate ions (one of the latter occupying the apical site). The three bridging C atoms and the two terminal C atoms of the Schiff base are disordered over two sets of sites, with occupancies of 0.465 (2) and 0.535 (2).
在标题配合物[Cu(NCS)₂(C₁₂H₁₉N₃)]中，Cu(II)原子呈五配位，具有由三齿席夫碱配体的一个吡啶N、一个亚胺N和一个胺N原子以及两个与N键合的硫氰酸根离子（其中一个硫氰酸根离子占据顶端位置）定义的四方锥几何构型。席夫碱的三个桥连C原子和两个端基C原子在两组位置上无序排列，占有率分别为0.465 (2)和0.535 (2)。
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