• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

链状多聚[[{N,N-二甲基-N'-[1-(吡啶-2-基)亚乙基]乙烷-1,2-二胺-κN,N',N''}(硫氰酸根-κN)镉]-μ-硫氰酸根-κS:N]

catena-Poly[[{N,N-dimethyl-N'-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}(thio-cyanato-κN)cadmium]-μ-thio-cyanato-κS:N].

作者信息

Suleiman Gwaram Nura, Khaledi Hamid, Mohd Ali Hapipah

机构信息

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m480. doi: 10.1107/S1600536811010063. Epub 2011 Mar 26.

DOI:10.1107/S1600536811010063
PMID:21753992
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3099776/
Abstract

In the title compound, Cd(NCS)(2)(C(11)H(17)N(3)), the Cd(II) atom is octa-hedrally coordinated by the N,N',N''-tridentate Schiff base ligand and one terminal thio-cyanate N atom. Two trans-N:S-bridging thio-cyanates complete the N(5)S donor set around the Cd atom. In the crystal, adjacent Cd(II) ions are linked by the thio-cyanate N:S-bridges into polymeric chains along the c axis.

摘要

在标题化合物[Cd(NCS)₂(C₁₁H₁₇N₃)]ₙ中，Cd(II)原子由N,N',N''-三齿席夫碱配体和一个末端硫氰酸根N原子八面体配位。两个反式-N:S桥连的硫氰酸根完成了围绕Cd原子的N(5)S供体集合。在晶体中，相邻的Cd(II)离子通过硫氰酸根N:S桥沿c轴连接成聚合物链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/61ce/3099776/b472f2e35279/e-67-0m480-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/61ce/3099776/b472f2e35279/e-67-0m480-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/61ce/3099776/b472f2e35279/e-67-0m480-fig1.jpg

相似文献

1
catena-Poly[[{N,N-dimethyl-N'-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}(thio-cyanato-κN)cadmium]-μ-thio-cyanato-κS:N].链状多聚[[{N,N-二甲基-N'-[1-(吡啶-2-基)亚乙基]乙烷-1,2-二胺-κN,N',N''}(硫氰酸根-κN)镉]-μ-硫氰酸根-κS:N]
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m480. doi: 10.1107/S1600536811010063. Epub 2011 Mar 26.
2
Di-μ-thio-cyanato-κN:S;κS:N-bis-({2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}(thio-cyanato-κN)cadmium).二-μ-硫氰酸根合-κN:S;κS:N-双-({2-吗啉代-N-[1-(2-吡啶基)亚乙基]乙胺-κN,N',N''}(硫氰酸根合-κN))镉
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 22;67(Pt 2):m251. doi: 10.1107/S1600536811002480.
3
Poly[bis(μ(3)-thio-cyanato-κN:S:S')(μ(2)-thio-cyanato-κN:S)(4'-p-tolyl-2,2':6',2''-terpyridine-κN,N',N'')cadmium(II)silver(I)].聚[双(μ(3)-硫氰酸根合-κN:S:S')(μ(2)-硫氰酸根合-κN:S)(4'-对甲苯基-2,2':6',2''-三联吡啶-κN,N',N'')镉(II)银(I)]
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 30;66(Pt 10):m1313-4. doi: 10.1107/S160053681003744X.
4
{N-Methyl-N'-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}-bis(thio-cyanato-κN)zinc(II).{N-甲基-N'-[1-(吡啶-2-基)亚乙基]乙烷-1,2-二胺-κN,N',N''}-双(硫氰酸根合-κN)锌(II)
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m829. doi: 10.1107/S1600536811019945. Epub 2011 Jun 4.
5
{N,N'-Bis[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N'',N'''}bis-(thio-cyanato-κN)manganese(II).{N,N'-双[1-(2-吡啶基)亚乙基]乙烷-1,2-二胺-κN,N',N'',N'''}双(硫氰酸根合-κN)锰(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m776. doi: 10.1107/S1600536810021550.
6
Bromido{N-methyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}-(thio-cyanato-κN)-copper(II).溴化{N-甲基-N'-[1-(2-吡啶基)亚乙基]乙烷-1,2-二胺-κN,N',N''}-(硫氰酸根-κN)-铜(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 17;66(Pt 8):m939. doi: 10.1107/S1600536810027534.
7
catena-Poly[[(2-{[2-(dimethyl-ammonio)-eth-yl]imino-meth-yl}pyridine-κ(2)N,N')bis-(thio-cyanato-κN)manganese(II)]-μ-thio-cyanato-κ(2)N:S].链状聚[[(2-{[2-(二甲基铵基)乙基]亚氨基甲基}吡啶-κ(2)N,N')双(硫氰酸根合-κN)锰(II)]-μ-硫氰酸根合-κ(2)N:S]
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1131. doi: 10.1107/S1600536812032874. Epub 2012 Jul 28.
8
{N,N'-Bis[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N'',N'''}(thio-cyanato-κN)zinc(II) perchlorate.高氯酸{N,N'-双[1-(2-吡啶基)亚乙基]乙烷-1,2-二胺-κN,N',N'',N'''}（硫氰酸根-κN）锌（II）
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m778-9. doi: 10.1107/S1600536810021628.
9
{N,N-Dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}bis-(thio-cyanato-κN)copper(II).{ N,N-二甲基-N'-[1-(2-吡啶基)亚乙基]乙烷-1,2-二胺-κN,N',N''}双(硫氰酸根合-κN)铜(II)
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m930. doi: 10.1107/S1600536811022057. Epub 2011 Jun 18.
10
catena-Poly[[di-μ-chlorido-bis-{[6-methoxy-2-(4-methyl-phenyl-iminio-methyl)phenolato-κO,O']cadmium(II)}]-di-μ(2)-thio-cyanato-κN:S;κS:N].链状聚[[二-μ-氯代-双-{[6-甲氧基-2-(4-甲基苯基亚氨基甲基)苯酚根合-κO,O']镉(II)}-二-μ(2)-硫氰酸根合-κN:S;κS:N]]
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 22;64(Pt 12):m1593-4. doi: 10.1107/S1600536808038099.

引用本文的文献

1
{N,N-Dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}bis-(thio-cyanato-κN)copper(II).{ N,N-二甲基-N'-[1-(2-吡啶基)亚乙基]乙烷-1,2-二胺-κN,N',N''}双(硫氰酸根合-κN)铜(II)
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m930. doi: 10.1107/S1600536811022057. Epub 2011 Jun 18.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.