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溴化（喹啉-8-醇-κN,O）（喹啉-8-醇根合-κN,O）锌（II）甲醇单溶剂合物

Bromido(quinolin-8-ol-κN,O)(quinolin-8-olato-κN,O)zinc(II) methanol monosolvate.

作者信息

Najafi Ezzatollah, Amini Mostafa M, Ng Seik Weng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 18;66(Pt 10):m1278. doi: 10.1107/S160053681003672X.

DOI:10.1107/S160053681003672X
PMID:21587422
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983236/
Abstract

The title compound, [ZnBr(C(9)H(6)NO)(C(9)H(7)NO)]·CH(3)OH, has its metal atom N,O-chelated by a neutral and a deproton-ated 8-hy-droxy-quinoline ligand. The hy-droxy unit of the neutral ligand is a hydrogen-bond donor to the methanol O atom and the alk-oxy O atom of the monoanionic ligand is a hydrogen-bond acceptor to the methanol O atom. In the crystal, adjacent mol-ecules are linked by these two hydrogen bonds, generating a chain running along the a axis.

摘要

标题化合物[ZnBr(C₉H₆NO)(C₉H₇NO)]·CH₃OH中，金属原子通过一个中性和一个去质子化的8-羟基喹啉配体进行N、O螯合。中性配体的羟基单元是甲醇O原子的氢键供体，单阴离子配体的烷氧基O原子是甲醇O原子的氢键受体。在晶体中，相邻分子通过这两个氢键相连，形成一条沿a轴延伸的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/70e5/2983236/3fd25dc3e1f3/e-66-m1278-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/70e5/2983236/3b88de57db0c/e-66-m1278-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/70e5/2983236/3fd25dc3e1f3/e-66-m1278-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/70e5/2983236/3b88de57db0c/e-66-m1278-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/70e5/2983236/3fd25dc3e1f3/e-66-m1278-fig2.jpg

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本文引用的文献

1
8-Hy-droxy-2-methyl-quinolinium dibromido(2-methyl-quinolin-8-olato-κN,O)zincate(II) methanol monosolvate.二溴化8-羟基-2-甲基喹啉鎓（2-甲基喹啉-8-醇根合-κN,O）锌酸盐（II）甲醇单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 18;66(Pt 10):m1276. doi: 10.1107/S1600536810036706.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.