溴化（喹啉-8-醇-κN,O）（喹啉-8-醇根合-κN,O）锌（II）甲醇单溶剂合物
Bromido(quinolin-8-ol-κN,O)(quinolin-8-olato-κN,O)zinc(II) methanol monosolvate.
作者信息
Najafi Ezzatollah, Amini Mostafa M, Ng Seik Weng
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 18;66(Pt 10):m1278. doi: 10.1107/S160053681003672X.
Abstract
The title compound, [ZnBr(C(9)H(6)NO)(C(9)H(7)NO)]·CH(3)OH, has its metal atom N,O-chelated by a neutral and a deproton-ated 8-hy-droxy-quinoline ligand. The hy-droxy unit of the neutral ligand is a hydrogen-bond donor to the methanol O atom and the alk-oxy O atom of the monoanionic ligand is a hydrogen-bond acceptor to the methanol O atom. In the crystal, adjacent mol-ecules are linked by these two hydrogen bonds, generating a chain running along the a axis.
摘要
标题化合物[ZnBr(C₉H₆NO)(C₉H₇NO)]·CH₃OH中，金属原子通过一个中性和一个去质子化的8-羟基喹啉配体进行N、O螯合。中性配体的羟基单元是甲醇O原子的氢键供体，单阴离子配体的烷氧基O原子是甲醇O原子的氢键受体。在晶体中，相邻分子通过这两个氢键相连，形成一条沿a轴延伸的链。
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本文引用的文献
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