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二溴化8-羟基-2-甲基喹啉鎓（2-甲基喹啉-8-醇根合-κN,O）锌酸盐（II）甲醇单溶剂合物

8-Hy-droxy-2-methyl-quinolinium dibromido(2-methyl-quinolin-8-olato-κN,O)zincate(II) methanol monosolvate.

作者信息

Najafi Ezzatollah, Amini Mostafa M, Ng Seik Weng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 18;66(Pt 10):m1276. doi: 10.1107/S1600536810036706.

DOI:10.1107/S1600536810036706
PMID:21587420
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983420/
Abstract

The anion of the title salt, (C(10)H(10)NO)[ZnBr(2)(C(10)H(8)NO)]·CH(3)OH, has its metal atom N,O-chelated by the deprotonated 2-methyl-8-hy-droxy-quinoline ligand. The hy-droxy unit of the cation is a hydrogen-bond donor to the alkoxide O atom of the tetra-hedrally coordinated anion, whereas the ammonium cation is a hydrogen-bond donor to the methano-lic O atom. In the crystal, adjacent ion pairs and solvent mol-ecules are linked by a methanol-halogen O-H⋯Br hydrogen bond, generating a chain running along the a axis.

摘要

标题盐（C(10)H(10)NO)[ZnBr(2)(C(10)H(8)NO)]·CH(3)OH的阴离子中，金属原子通过去质子化的2-甲基-8-羟基喹啉配体进行N,O-螯合。阳离子的羟基单元是与四面体配位阴离子的醇盐O原子形成氢键的供体，而铵阳离子是与甲醇的O原子形成氢键的供体。在晶体中，相邻的离子对和溶剂分子通过甲醇-卤素O-H⋯Br氢键相连，形成沿a轴延伸的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9cf3/2983420/7e2401e6d9c9/e-66-m1276-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9cf3/2983420/7e2401e6d9c9/e-66-m1276-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9cf3/2983420/7e2401e6d9c9/e-66-m1276-fig1.jpg

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本文引用的文献

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8-Hydr-oxy-2-methyl-quinolinium dichlorido(2-methyl-quinolin-8-olato-κN,O)zincate(II) methanol solvate.二氯（2-甲基喹啉-8-醇根-κN,O）锌酸（II）-8-羟基-2-甲基喹啉鎓甲醇溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 22;65(Pt 5):m553. doi: 10.1107/S1600536809014202.
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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
二氯（2-甲基喹啉-8-醇根-κN,O）锌（II）8-羟基-2-甲基喹啉鎓乙腈溶剂化物
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4
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