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二氯（2-甲基喹啉-8-醇根-κN,O）锌（II）8-羟基-2-甲基喹啉鎓乙腈溶剂化物

8-Hy-droxy-2-methyl-quinolinium dichlorido(2-methyl-quinolin-8-olato-κN,O)zincate acetonitrile disolvate.

作者信息

Najafi Ezzatollah, Amini Mostafa M, Ng Seik Weng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1280. doi: 10.1107/S1600536811032338. Epub 2011 Aug 27.

DOI:10.1107/S1600536811032338
PMID:22058876
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3200945/
Abstract

The reaction of 2-methyl-8-hy-droxy-quinoline and zinc chloride in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[Zn(C(10)H(8)NO)Cl(2)]·2CH(3)CN, in which the Zn(II) atom is coordinated by an- N,O-chelating 2-methyl-quinolin-8-olate ligand and two chloride ligands in a distorted tetra-hedral geometry. The cation is linked to the heterocyclic anion by an O-H⋯O hydrogen bond and the quinolinium H atom forms a inter-molecular N-H⋯N hydrogen bond with one of the acetonitrile solvent mol-ecules.

摘要

2-甲基-8-羟基喹啉与氯化锌在乙腈中的反应得到标题溶剂化盐，(C₁₀H₁₀NO)[Zn(C₁₀H₈NO)Cl₂]·2CH₃CN，其中Zn(II)原子由一个N,O-螯合的2-甲基喹啉-8-醇盐配体和两个氯配体以扭曲的四面体几何构型配位。阳离子通过O-H⋯O氢键与杂环阴离子相连，喹啉鎓H原子与其中一个乙腈溶剂分子形成分子间N-H⋯N氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5c39/3200945/b44247115d60/e-67-m1280-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5c39/3200945/b44247115d60/e-67-m1280-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5c39/3200945/b44247115d60/e-67-m1280-fig1.jpg

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本文引用的文献

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