Pourayoubi Mehrdad, Tarahhomi Atekeh, Rheingold Arnold L, Golen James A
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 11;66(Pt 10):o2524. doi: 10.1107/S1600536810035725.
The phosphoryl and carbonyl groups in the title compound, C(23)H(24)F(2)N(3)O(2)P, are anti to each other. The P atom is in a tetra-hedral coordination environment and the environment of each N atom is essentially planar, the average bond angles at the two N atoms being 119.9 and 119.1°. The H atom of the C(=O)NHP(=O) group is involved in an inter-molecular -P=O⋯H-N- hydrogen bond, forming centrosymmetric dimers.
标题化合物C₂₃H₂₄F₂N₃O₂P中的磷酰基和羰基彼此呈反式。P原子处于四面体配位环境中,每个N原子的环境基本为平面,两个N原子处的平均键角分别为119.9°和119.1°。C(=O)NHP(=O)基团的H原子参与分子间-P=O⋯H-N-氢键,形成中心对称二聚体。