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(μ-草酸根-κO,O:O,O)双[双(2,2'-联吡啶-κN,N')钴(II)] μ(6)-氧化十二-μ(2)-氧化六-氧化六钨酸(VI)

(μ-Oxalato-κO,O:O,O)bis-[bis-(2,2'-bipyridine-κN,N')cobalt(II)] μ(6)-oxido-dodeca-μ(2)-oxido-hexa-oxido-hexa-tungstate(VI).

作者信息

Shi Congwen, Fan Liming, Wei Peihai, Li Bin, Zhang Xiutang

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 18;66(Pt 7):m822-3. doi: 10.1107/S1600536810023007.

Abstract

The asymmetric unit of the title compound, [Co(2)(C(2)O(4))(C(10)H(8)N(2))(4)][W(6)O(19)], consists of one half of the complex Co(2)(C(2)O(4))(C(10)H(8)N(2))(4) cation and one half of the Lindqvist-type W(6)O(19) isopolyanion. Both constituents are completed by crystallographic inversion symmetry. In the dimeric cation, the Co(II) atom is surrounded in a distorted octa-hedral coordination by four N atoms from two chelating 2,2'-bipyridine ligands and by two O atoms from the chelating oxalate anion. The Lindqvist-type anion exhibits the characteristic W-O bond-length distribution, with the shortest bonds being the W-O(terminal) bonds and the longest being those to the central O atom.

摘要

标题化合物[Co₂(C₂O₄)(C₁₀H₈N₂)₄][W₆O₁₉]的不对称单元由配合物[Co₂(C₂O₄)(C₁₀H₈N₂)₄]²⁺阳离子的一半和Lindqvist型[W₆O₁₉]²⁻异多阴离子的一半组成。这两种成分均通过晶体学倒转对称性得以完整。在二聚阳离子中,Co(II)原子由来自两个螯合2,2'-联吡啶配体的四个N原子以及来自螯合草酸根阴离子的两个O原子以扭曲的八面体配位方式环绕。Lindqvist型阴离子呈现出特征性的W - O键长分布,最短的键是W - O(端基)键,最长的键是与中心O原子相连的键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e9c8/3006761/57f8e345a743/e-66-0m822-fig1.jpg

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本文引用的文献

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catena-Poly[[(2,2'-bipyridine-κN,N')cobalt(II)]-μ-oxalato-κO,O:O,O].
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 10;65(Pt 5):m508. doi: 10.1107/S1600536809012690.
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Diaqua-1κO,2κO-(2,2'-bi-1H-imidazole-1κN,N)(oxalato-2κO,O)di-μ-oxido-κO:O-dioxido-1κO,2κO-dimolyb-denum(V) trihydrate.
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 9;66(Pt 1):m26-7. doi: 10.1107/S1600536809052003.
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A short history of SHELX.
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.

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