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链状聚[[[(2-苯基乙酸根-κO)锌(II)]双-[μ-4,4'-(二硫烷二基)二吡啶-κN:N']]一水合物]

catena-Poly[[[(2-phenyl-acetato-κO)zinc(II)]bis-[μ-4,4'-(disulfanedi-yl)dipyridine-κN:N']] monohydrate].

作者信息

Zhang Jie, Xu Wei

机构信息

State Key Laboratory Base of Novel Functional Materials and Preparation Science, Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo, Zhejiang 315211, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m788-9. doi: 10.1107/S1600536810021331.

DOI:10.1107/S1600536810021331
PMID:21587713
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3007060/
Abstract

In the title compound, {[Zn(C(8)H(7)O(2))(2)(C(10)H(8)N(2)S(2))(2)]·H(2)O}(n), the Zn(II) atom is coordinated by four N atoms from four 4,4'-(disulfanedi-yl)dipyridine (bpds) ligands and two O atoms from two 2-phenyl-acetate anions in a distorted octa-hedral coordination geometry. The two bpds ligands of the same axial chirality bridge Zn(II) atoms, generating repeated rhomboidal chains, which are linked by O-H⋯O hydrogen bonds into a ladder structure.

摘要

在标题化合物{[Zn(C₈H₇O₂)₂(C₁₀H₈N₂S₂)₂]·H₂O}ₙ中，Zn(II)原子由四个4,4'-(二硫烷二亚基)二吡啶(bpds)配体的四个N原子和两个2-苯基乙酸根阴离子的两个O原子以扭曲的八面体配位几何构型配位。两个具有相同轴向手性的bpds配体桥连Zn(II)原子，形成重复的菱形链，这些链通过O—H⋯O氢键连接成梯形结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c17/3007060/84240209c67e/e-66-0m788-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c17/3007060/f4f8d562af56/e-66-0m788-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c17/3007060/5c3c40f3b88c/e-66-0m788-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c17/3007060/84240209c67e/e-66-0m788-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c17/3007060/f4f8d562af56/e-66-0m788-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c17/3007060/5c3c40f3b88c/e-66-0m788-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c17/3007060/84240209c67e/e-66-0m788-fig3.jpg

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本文引用的文献

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Crystal engineering of coordination polymers using 4,4'-bipyridine as a bond between transition metal atoms.以4,4'-联吡啶作为过渡金属原子间的连接键对配位聚合物进行晶体工程。
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