Zhu Hong-Lin, Zhang Jie, Lin Jian-Li
State Key Laboratory Base of Novel Functional Materials and Preparation Science, Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo, Zhejiang 315211, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 20;66(Pt 2):m185. doi: 10.1107/S1600536810001716.
The asymmetric unit of the title compound, {Cu(C(10)H(8)N(2)S(2))(2)(H(2)O)(2)(2)·H(2)O}(n), contains one Cu(II) ion, two bridging di-4-pyridyl disulfide (4-DPDS) ligands of the same chirality, two coordinating water mol-ecules, two hydrogen phthalate anions and one uncoordinated water mol-ecule. The polymeric structure consists of two types of polymeric chains, each composed from repeated chiral rhomboids. The Cu(II) ions adopt a distorted octa-hedral coordination geometry and are coordinated by four pyridine N atoms and two water O atoms. The coordinated water mol-ecules and hydrogen phthalate anions are located between the repeated rhomboidal chains, and form hydrogen bonds with the coordinated water mol-ecules.
标题化合物{Cu(C₁₀H₈N₂S₂)₂(H₂O)₂₂·H₂O}ₙ的不对称单元包含一个Cu(II)离子、两个具有相同手性的桥联二(4 - 吡啶基)二硫化物(4 - DPDS)配体、两个配位水分子、两个邻苯二甲酸氢根阴离子和一个未配位的水分子。聚合物结构由两种类型的聚合物链组成，每种链由重复的手性菱形构成。Cu(II)离子采用扭曲的八面体配位几何构型，由四个吡啶N原子和两个水O原子配位。配位水分子和邻苯二甲酸氢根阴离子位于重复的菱形链之间，并与配位水分子形成氢键。
