硝酸六（二甲亚砜-κO）铊（III）
Hexa-kis-(dimethyl sulfoxide-κO)thallium(III) trinitrate.
作者信息
Ghadermazi Mohammad, Manteghi Faranak
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 18;66(Pt 7):m812. doi: 10.1107/S1600536810022646.
Abstract
The title compound, Tl(C(2)H(6)OS)(6)(3), consists of six dimethyl sulfoxide (DMSO) mol-ecules coordinated to a Tl(III) atom, which lies on a axis, and three nitrate anions (3. symmetry) to neutralize the charge. The coordination polyhedron around the Tl(III) atom is octa-hedral, defined by six O atoms of the DMSO mol-ecules. In the crystal structure, C-H⋯O hydrogen bonds are observed. One of the nitrate groups exhibits half-occupation.
摘要
标题化合物Tl(C₂H₆OS)₆₃由六个与位于a轴上的Tl(III)原子配位的二甲基亚砜（DMSO）分子和三个硝酸根阴离子（3. 对称性）组成，以中和电荷。Tl(III)原子周围的配位多面体为八面体，由DMSO分子的六个O原子定义。在晶体结构中，观察到C-H⋯O氢键。其中一个硝酸根基团呈现半占据状态。
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