Tomyn Stefania, Gumienna-Kontecka Elżbieta, Usenko Natalia I, Iskenderov Turganbay S, Prisyazhnaya Elena V
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1774-5. doi: 10.1107/S1600536811048082. Epub 2011 Nov 19.
In the mononuclear title complex, Zn(C(10)H(8)N(2))(2)(C(2)H(6)OS)(2)(2)·C(2)H(6)OS, the Zn(II) ion is coordinated by four N atoms of two bidentate 2,2'-bipyridine mol-ecules and by the O atoms of two cis-disposed dimethyl sulfoxide mol-ecules in a distorted octa-hedral geometry. The S atom and the methyl groups of one of the coordinated dimethyl sulfoxide mol-ecules are disordered in a 0.509 (2):0.491 (2) ratio. The crystal packing is stabilized by C-H⋯O hydrogen bonds between the dimethyl sulfoxide solvent mol-ecules and tetra-phenyl-borate anions.
在单核标题配合物Zn(C₁₀H₈N₂)₂(C₂H₆OS)₂₂·C₂H₆OS中,Zn(II)离子由两个双齿2,2'-联吡啶分子的四个N原子以及两个顺式排列的二甲基亚砜分子的O原子配位,形成扭曲的八面体几何构型。一个配位的二甲基亚砜分子的S原子和甲基以0.509 (2):0.491 (2)的比例无序排列。晶体堆积通过二甲基亚砜溶剂分子与四苯基硼酸根阴离子之间的C-H⋯O氢键得以稳定。