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顺式双(2,2'-联吡啶-κN,N')双(二甲亚砜-κO)锌双(四苯基硼酸)二甲亚砜单溶剂合物

cis-Bis(2,2'-bipyridine-κN,N')bis-(dimethyl sulfoxide-κO)zinc bis-(tetra-phenyl-borate) dimethyl sulfoxide monosolvate.

作者信息

Tomyn Stefania, Gumienna-Kontecka Elżbieta, Usenko Natalia I, Iskenderov Turganbay S, Prisyazhnaya Elena V

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1774-5. doi: 10.1107/S1600536811048082. Epub 2011 Nov 19.

Abstract

In the mononuclear title complex, Zn(C(10)H(8)N(2))(2)(C(2)H(6)OS)(2)(2)·C(2)H(6)OS, the Zn(II) ion is coordinated by four N atoms of two bidentate 2,2'-bipyridine mol-ecules and by the O atoms of two cis-disposed dimethyl sulfoxide mol-ecules in a distorted octa-hedral geometry. The S atom and the methyl groups of one of the coordinated dimethyl sulfoxide mol-ecules are disordered in a 0.509 (2):0.491 (2) ratio. The crystal packing is stabilized by C-H⋯O hydrogen bonds between the dimethyl sulfoxide solvent mol-ecules and tetra-phenyl-borate anions.

摘要

在单核标题配合物Zn(C₁₀H₈N₂)₂(C₂H₆OS)₂₂·C₂H₆OS中,Zn(II)离子由两个双齿2,2'-联吡啶分子的四个N原子以及两个顺式排列的二甲基亚砜分子的O原子配位,形成扭曲的八面体几何构型。一个配位的二甲基亚砜分子的S原子和甲基以0.509 (2):0.491 (2)的比例无序排列。晶体堆积通过二甲基亚砜溶剂分子与四苯基硼酸根阴离子之间的C-H⋯O氢键得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/33b2/3238690/478370b8d241/e-67-m1774-fig1.jpg

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