2-[(1,3-苯并噻唑-2-基)亚氨基甲基]苯酚的单斜变体。
A monoclinic modification of 2-[(1,3-benzothia-zol-2-yl)imino-meth-yl]phenol.
作者信息
Asiri Abdullah M, Khan Salman A, Tan Kong Wai, Ng Seik Weng
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 26;66(Pt 7):o1826. doi: 10.1107/S1600536810023755.
In the title Schiff base, C(14)H(10)N(2)OS, the azomethine double bond is in an E configuration; the benzothiazolyl ring (r.m.s. deviation = 0.007 Å) is coplanar with the phenyl-ene ring (r.m.s. deviation = 0.007 Å), the two rings being slightly bent at 2.6 (1)°. The hy-droxy H atom forms an intra-molecular hydrogen bond to the imino group. The bond dimensions of the monoclinic modification are similar to those of the ortho-rhom-bic modification [Liu et al. (2009 ▶). Acta Cryst. E65, o738].
在席夫碱C(14)H(10)N(2)OS的标题中，偶氮甲碱双键呈E构型；苯并噻唑环（均方根偏差 = 0.007 Å）与亚苯基环（均方根偏差 = 0.007 Å）共面，两个环以2.6 (1)°轻微弯曲。羟基H原子与亚氨基形成分子内氢键。单斜变体的键尺寸与正交变体的键尺寸相似[Liu等人（2009 ▶）。《晶体学报》E65，o738]。
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