2-{[2-(4-氯苯基)肼叉基]甲基}苯酚
2-{[2-(4-Chloro-phen-yl)hydrazinyl-idene]meth-yl}phenol.
作者信息
Lo Kong Mun, Ng Seik Weng
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1452. doi: 10.1107/S1600536811017958. Epub 2011 May 20.
Abstract
In the title Schiff base mol-ecule, C(13)H(11)ClN(2)O, the non-H atoms are approximately coplanar (r.m.s. deviation = 0.115 Å) and the two benzene rings are twisted by 9.36 (3)° with respect to each other. The hy-droxy group is hydrogen bonded to the azomethine N atom. In the crystal, an N-H⋯π inter-action is observed between the imino group and the hy-droxy-benzene ring of an adjacent mol-ecule.
摘要
在席夫碱分子C(13)H(11)ClN(2)O中，非氢原子近似共面（均方根偏差 = 0.115 Å），两个苯环相对于彼此扭转了9.36 (3)°。羟基与甲亚胺N原子形成氢键。在晶体中，观察到亚氨基与相邻分子的羟基苯环之间存在N-H⋯π相互作用。
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