1,3-双（1-金刚烷基）咪唑四氯合铁（III）酸盐
1,3-Bis(1-adamant-yl)imidazolium tetra-chloridoferrate(III).
作者信息
Ikhile Monisola I, Bala Muhammad D
机构信息
School of Chemistry, University of KwaZulu-Natal, Westville Campus, Private Bag X54001, Durban 4000, South Africa.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 31;66(Pt 11):m1493. doi: 10.1107/S1600536810043989.
The crystal structure of the title compound, (C(23)H(33)N(2))[FeCl(4)], consists of 1,3-bis-(1-adamant-yl)imidazolium (BAIM) cations and tetra-hedral tetra-chloridoferrate(III) (TCF) anions. The BAIM cation possesses m symmetry, with the central imidazole ring and four C atoms of each terminal adamantyl group located on a mirror plane. The Fe and two Cl atoms of the TCF anion are also located on the mirror plane. The cyclo-hexane rings of the adamantyl groups adopt normal chair conformations.
标题化合物（C₂₃H₃₃N₂）[FeCl₄]的晶体结构由1,3-双（1-金刚烷基）咪唑鎓（BAIM）阳离子和四面体四氯合铁（III）（TCF）阴离子组成。BAIM阳离子具有m对称性，中心咪唑环和每个末端金刚烷基的四个C原子位于一个镜面上。TCF阴离子的Fe和两个Cl原子也位于镜面上。金刚烷基的环己烷环呈正常的椅式构象。
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