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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.

[双（二苯基膦基）二甲基硅烷-κP,P']四羰基铬(0)

[Bis(diphenyl-phosphan-yl)dimethyl-silane-κP,P']tetra-carbonyl-chromium(0).

作者信息

Peulecke Normen, Peitz Stephan, Müller Bernd H, Spannenberg Anke, Rosenthal Uwe

机构信息

Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 31;66(Pt 11):m1494. doi: 10.1107/S1600536810043679.

DOI:10.1107/S1600536810043679
PMID:21588907
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3009008/
Abstract

The title compound, [Cr(C(26)H(26)P(2)Si)(CO)(4)], was obtained by the reaction of Ph(2)PSiMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by ligand exchange. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa-hedral, with a P-Cr-P bite angle of 80.27 (1)°.

摘要

标题化合物[Cr(C₂₆H₂₆P₂Si)(CO)₄]是通过二苯基膦硅基二甲基二苯基膦（Ph₂PSiMe₂PPh₂）与六羰基铬（Cr(CO)₆）在回流甲苯中进行配体交换反应制得的。Cr原子处的CrC₄P₂配位几何构型为扭曲的八面体，P-Cr-P咬角为80.27 (1)°。