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高氯酸4-溴苯胺-18-冠-6包合物

4-Bromo-anilinium perchlorate 18-crown-6 clathrate.

作者信息

Guo Min, Zhao Min Min

机构信息

Ordered Matter Science Research Center, College of Chemistry and Chemical, Engineering, Southeast University, Nanjing 211189, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 20;66(Pt 11):o2836. doi: 10.1107/S1600536810040481.

DOI:10.1107/S1600536810040481
PMID:21589022
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3009328/
Abstract

The reaction of 4-bromo-aniline, 18-crown-6, and perchloric acid in methanol yields the title compound, C(6)H(7)BrN(+)·ClO(4) (-)·C(12)H(24)O(6), in which the protonated -NH(3) (+) group forms three bifurcated N-H⋯O hydrogen bonds to the O atoms of the crown ether.

摘要

4-溴苯胺、18-冠-6与高氯酸在甲醇中反应生成标题化合物C₆H₇BrN⁺·ClO₄⁻·C₁₂H₂₄O₆，其中质子化的-NH₃⁺基团与冠醚的O原子形成三个分叉的N-H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/479e/3009328/8ef7582ae5ff/e-66-o2836-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/479e/3009328/35e50e36d8da/e-66-o2836-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/479e/3009328/8ef7582ae5ff/e-66-o2836-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/479e/3009328/35e50e36d8da/e-66-o2836-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/479e/3009328/8ef7582ae5ff/e-66-o2836-fig2.jpg

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