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双{μ-2,2'-[乙烷-1,2-二基双(腈基亚甲基)]二酚根合}双[(硫氰酸根合)锰(III)]。

Bis{μ-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}bis-[(thio-cyanato)manganese(III)].

作者信息

Wang Shou-Bin, Tang Kun, Yang Bao-Hua, Li Sheng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 14;64(Pt 4):m543. doi: 10.1107/S1600536808003577.

DOI:10.1107/S1600536808003577
PMID:21202001
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960991/
Abstract

The reported structure is a monoclinic polymorph of the title compound, [Mn(2)(C(16)H(14)N(2)O(2))(2)(NCS)(2)], which has been characterized previously in an ortho-rhom-bic form. Each Mn(III) atom is chelated by a tetra-dentate 2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate ligand and by the N atom of a thio-cyanate anion, in a square-pyramidal arrangement. The complexes form centrosymmetric dimers, with an Mn-O contact of 2.557 (3) Å trans to each thio-cyanate anion, completing a distorted octa-hedral coordination geometry.

摘要

所报道的结构是标题化合物[Mn₂(C₁₆H₁₄N₂O₂)₂(NCS)₂]的单斜晶多晶型物，该化合物先前已被表征为正交晶型。每个Mn(III)原子由一个四齿的2,2'-[乙烷-1,2-二基双(亚氨基甲基亚基)]二酚盐配体和一个硫氰酸根阴离子的N原子螯合，呈四方锥排列。这些配合物形成中心对称的二聚体，与每个硫氰酸根阴离子反式的Mn-O接触距离为2.557 (3) Å，形成扭曲的八面体配位几何结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ac07/2960991/79a4e4c6f9c0/e-64-0m543-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ac07/2960991/79a4e4c6f9c0/e-64-0m543-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ac07/2960991/79a4e4c6f9c0/e-64-0m543-fig1.jpg

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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
Bis{μ-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}bis-[(thio-cyanato-κN)iron(III)].
双{μ-2,2'-[乙烷-1,2-二基双(腈基亚甲基)]二酚根合}双[(硫氰酸根-κN)铁(III)]
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 16;64(Pt 8):m1034. doi: 10.1107/S1600536808021892.