Huang Chiung-Cheng, Chen Han-Gung, Lo Yih Hsing, Hsu Li-Sheng, Lin Chia-Her
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m795-6. doi: 10.1107/S1600536810021525.
In the title compound, [Ru(C(9)H(10)BN(6))Cl(C(3)H(4)N(2))(C(18)H(15)P)], the Ru(II) atom is coordinated by an N,N',N''-tridentate hydrido-trispyrazolylborate (Tp) ligand, a pyrazole (HPz) mol-ecule, a chloride ion and a triphenyl-phosphine ligand, resulting in a distorted RuClPN(4) octa-hedral coordination for the metal ion: the tridentate N atoms occupy one octa-hedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547 (10):0.453 (10) ratio, and a weak intra-molecular N-H⋯Cl hydrogen bond generates an S(5) ring.
在标题化合物[Ru(C₉H₁₀BN₆)Cl(C₃H₄N₂)(C₁₈H₁₅P)]中，Ru(II)原子由一个N,N',N''-三齿氢化三吡唑基硼酸酯（Tp）配体、一个吡唑（HPz）分子、一个氯离子和一个三苯基膦配体配位，导致金属离子形成扭曲的RuClPN₄八面体配位：三齿N原子占据一个八面体面，Cl和P原子是顺式的。其中一个苯环在两种取向上无序，比例为0.547 (10):0.453 (10)，并且一个弱的分子内N-H⋯Cl氢键形成一个S(5)环。
