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链状聚[铅（II）-双-（μ-2-氨基-1,3-苯并噻唑-6-羧酸根）]

catena-Poly[lead(II)-bis-(μ-2-amino-1,3-benzothia-zole-6-carboxyl-ato)].

作者信息

Zhang Ke-Ke, Fang Xin, Yu Hai-Yang, Ke Hua, Wang Jun-Dong

机构信息

College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 30;66(Pt 12):m1700-1. doi: 10.1107/S1600536810049330.

DOI:10.1107/S1600536810049330
PMID:21589352
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3011691/
Abstract

The title complex, Pb(C(8)H(5)N(2)O(2)S)(2), consists of one Pb(II) ion located on a crystallographic twofold axis and two symmetry-related 2-amino-1,3-benzothia-zole-6-carboxyl-ate (ABTC) ligands. The central Pb(II) ion has a (4 + 2) coordination by four O atoms of the two ABTC ligands and two weaker Pb-S bonding inter-actions (Pb-S secondary bonds) from S atoms of other two neighbouring ABTC ligands. These bonds link the metal ions into zigzag chains along the c axis, which, in turn, aggregate through π-π inter-actions [centroid-centroid distance = 3.7436 Å] between ABTC rings and N-H⋯O and N-H⋯N hydrogen bonds.

摘要

标题配合物[Pb(C₈H₅N₂O₂S)₂]ₙ由位于晶体学二重轴上的一个Pb(II)离子和两个对称相关的2-氨基-1,3-苯并噻唑-6-羧酸酯（ABTC）配体组成。中心Pb(II)离子通过两个ABTC配体的四个O原子形成(4 + 2)配位，以及来自其他两个相邻ABTC配体的S原子的两个较弱的Pb-S键相互作用（Pb-S二级键）。这些键沿着c轴将金属离子连接成锯齿链，这些链又通过ABTC环之间的π-π相互作用[质心-质心距离 = 3.7436 Å]以及N-H⋯O和N-H⋯N氢键聚集。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b9/3011691/c5e1557915c4/e-66-m1700-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b9/3011691/1a4e96ecbb54/e-66-m1700-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b9/3011691/b65b65fbae73/e-66-m1700-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b9/3011691/c5e1557915c4/e-66-m1700-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b9/3011691/1a4e96ecbb54/e-66-m1700-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b9/3011691/b65b65fbae73/e-66-m1700-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b9/3011691/c5e1557915c4/e-66-m1700-fig3.jpg

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1
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J Appl Crystallogr. 2021 Sep 29;54(Pt 5):1535-1541. doi: 10.1107/S1600576721008529. eCollection 2021 Oct 1.
2
Ethyl 2-(tert-butoxy-carbonyl-amino)-1,3-benzothia-zole-6-carboxyl-ate.2-（叔丁氧羰基氨基）-1,3-苯并噻唑-6-羧酸乙酯
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 24;66(Pt 4):o914. doi: 10.1107/S160053681001024X.
3
tert-Butyl N-[6-(N,N-dipropyl-carbamo-yl)-1,3-benzothia-zol-2-yl]carbamate.
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Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 30;66(Pt 5):o1239-40. doi: 10.1107/S160053681001528X.
4
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J Med Chem. 2010 Jun 24;53(12):4633-41. doi: 10.1021/jm1001293.
5
Novel cyano- and amidinobenzothiazole derivatives: synthesis, antitumor evaluation, and X-ray and quantitative structure-activity relationship (QSAR) analysis.新型氰基和脒基苯并噻唑衍生物：合成、抗肿瘤评估以及X射线和定量构效关系（QSAR）分析
J Med Chem. 2009 Mar 26;52(6):1744-56. doi: 10.1021/jm801566q.
6
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
7
Semiconducting lead-sulfur-organic network solids.
J Am Chem Soc. 2008 Jan 9;130(1):14-5. doi: 10.1021/ja0770983. Epub 2007 Dec 8.
8
Two isomers of Pd2(S2NC7H4)4.
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9
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Bioorg Med Chem Lett. 2003 Jul 7;13(13):2145-9. doi: 10.1016/s0960-894x(03)00380-9.