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（E）-N'-（5-溴-2-甲氧基-亚苄基）-4-甲氧基-苯甲酰肼

(E)-N'-(5-Bromo-2-methoxy-benzyl-idene)-4-methoxy-benzohydrazide.

作者信息

Ban Hong-Yan, Li Cong-Ming

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 8;64(Pt 12):o2260. doi: 10.1107/S1600536808035472.

DOI:10.1107/S1600536808035472
PMID:21581241
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959874/
Abstract

In the title compound, C(16)H(15)BrN(2)O(3), the benzohydrazide group is not planar and the mol-ecule exists in a trans configuration with respect to the methyl-idene unit. The dihedral angle between the two substituted benzene rings is 75.6 (2)°. In the crystal structure, mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds involving carbonyl and amine functionalities, to form chains parallel to the c cell axis.

摘要

在标题化合物C(16)H(15)BrN(2)O(3)中，苯甲酰肼基团不是平面的，并且分子相对于亚甲基单元以反式构型存在。两个取代苯环之间的二面角为75.6 (2)°。在晶体结构中，分子通过涉及羰基和胺官能团的分子间N-H⋯O氢键相连，形成平行于c轴的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2df/2959874/f60c2c3f7841/e-64-o2260-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2df/2959874/b22df8c7b474/e-64-o2260-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2df/2959874/f60c2c3f7841/e-64-o2260-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2df/2959874/b22df8c7b474/e-64-o2260-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2df/2959874/f60c2c3f7841/e-64-o2260-fig2.jpg

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