Laboratoire Réactions et Génie des Procédés (LRGP), CNRS, Nancy Université, ENSIC, 1, rue Grandville, BP 20451, 54001 NANCY Cedex, France.
Chem Soc Rev. 2011 Sep;40(9):4762-82. doi: 10.1039/c0cs00207k. Epub 2011 May 19.
In the context of limiting the environmental impact of transportation, this critical review discusses new directions which are being followed in the development of more predictive and more accurate detailed chemical kinetic models for the combustion of fuels. In the first part, the performance of current models, especially in terms of the prediction of pollutant formation, is evaluated. In the next parts, recent methods and ways to improve these models are described. An emphasis is given on the development of detailed models based on elementary reactions, on the production of the related thermochemical and kinetic parameters, and on the experimental techniques available to produce the data necessary to evaluate model predictions under well defined conditions (212 references).
在限制交通运输对环境的影响方面，本综述讨论了在开发更具预测性和更精确的燃料燃烧详细化学动力学模型方面所遵循的新方向。在第一部分中，评估了当前模型的性能，特别是在预测污染物形成方面的性能。在接下来的部分中，描述了最近改进这些模型的方法和途径。重点放在基于基本反应的详细模型的开发上，放在相关热化学和动力学参数的产生上，以及放在可用于在明确定义的条件下产生评估模型预测所需的数据的实验技术上（212 篇参考文献）。
