State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China.
Chem Soc Rev. 2011 Jul;40(7):4244-58. doi: 10.1039/c1cs15026j. Epub 2011 May 20.
The attachment strategy based on catecholic chemistry has been arousing renewed interest since the work on polymerized catecholic amine (polydopamine) (Messersmith et al., Science, 2007, 318, 426) was published. Catechols and their derived compounds can self-assemble on various inorganic and organic materials, including noble metals, metals, metal oxides, mica, silica, ceramics and even polymers. It opens a new route to the modification of various substrates and the preparation of functional composite materials by simple chemistry. However, there is still not a full review so far about the attachment chemistry despite the dramatically increasing number of publications. This critical review describes the state-of-the-art research in the area: the design and synthesis of catecholic molecules, their adsorption mechanisms and the stability of assemblies in solution, and their applications etc. Some perspectives on future development are raised (195 references).
基于儿茶酚化学的附着策略自聚合物儿茶酚胺（聚多巴胺）（Messersmith 等人，《科学》，2007，318，426）的工作发表以来，重新引起了人们的兴趣。儿茶酚及其衍生化合物可以在各种无机和有机材料上自组装，包括贵金属、金属、金属氧化物、云母、二氧化硅、陶瓷，甚至聚合物。它为通过简单的化学方法修饰各种基质和制备功能复合材料开辟了新途径。然而，尽管出版物数量急剧增加，但迄今为止，关于附着化学仍没有全面的综述。这篇评论性文章描述了该领域的最新研究进展：儿茶酚分子的设计和合成、它们在溶液中的吸附机制和组装体的稳定性，以及它们的应用等。还提出了一些对未来发展的展望（195 篇参考文献）。
