Department of Chemistry, Tulane University, New Orleans, LA 70118, USA.
Chem Commun (Camb). 2011 Aug 28;47(32):9036-8. doi: 10.1039/c1cc11259g. Epub 2011 May 20.
The surface modification of deep-cavity cavitands has been demonstrated by using the azide-alkyne "click" coupling to attach dendritic macromolecules or linear polymers onto their periphery. The resulting set of macromolecular cavitands exhibited tuneable solubility yet retained the ability to encapsulate guest molecules.
通过使用叠氮-炔基“点击”偶联反应，将树枝状大分子或线性聚合物连接到其外围，实现了深腔穴状配体的表面修饰。所得的一组大分子穴状配体具有可调的溶解性，但仍保留了包封客体分子的能力。
