连续点击反应作为一种通用路线制备功能性环状聚酯。
Two consecutive click reactions as a general route to functional cyclic polyesters.
机构信息
Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China.
出版信息
Chem Commun (Camb). 2012 Jan 14;48(4):570-2. doi: 10.1039/c1cc16065f. Epub 2011 Nov 7.
A simple and universal route to functional cyclic polyesters has been demonstrated, combining two consecutive click reactions of azide-alkyne cycloaddition of linear hetero-bifunctional precursors and thiol-ene coupling for post cyclization functionalizations. Functional cationic and thermo-responsive cyclic polyphosphoesters have been synthesized to demonstrate the efficiency of the procedures.
已经证明了一种简单而通用的功能性环状聚酯的合成途径，该途径结合了线性杂双官能团前体的叠氮-炔点击反应和环化后官能化的硫醇-烯加成反应的两个连续点击反应。已经合成了功能性阳离子和热敏性环状聚磷酸酯，以证明该方法的效率。
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