Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA.
Org Biomol Chem. 2011 Jul 7;9(13):4741-4. doi: 10.1039/c0ob01189d. Epub 2011 May 23.
Hydrogen peroxide was employed as the terminal oxidant in the osmium tetroxide mediated oxidative cleavage of olefins, producing the corresponding aldehyde and ketone products. Aryl olefins are cleaved in good to excellent yield regardless of arene electronics. Alkyl olefins cleave in moderate to good yield for di- and tri-substituted alkenes.
过氧化氢被用作四氧化锇介导的烯烃氧化裂解中的末端氧化剂，生成相应的醛和酮产物。芳基烯烃无论芳环电子如何都能以良好到优异的收率裂解。二取代和三取代烯烃的烷基烯烃以中等至良好的收率裂解。
