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单原子模型系统中的液-液相转变和玻璃化转变

Liquid-liquid phase transition and glass transition in a monoatomic model system.

作者信息

Xu Limei, Buldyrev Sergey V, Giovambattista Nicolas, Stanley H Eugene

机构信息

WPI Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan.

出版信息

Int J Mol Sci. 2010;11(12):5184-200. doi: 10.3390/ijms11125184. Epub 2010 Dec 16.

Abstract

We review our recent study on the polyamorphism of the liquid and glass states in a monatomic system, a two-scale spherical-symmetric Jagla model with both attractive and repulsive interactions. This potential with a parametrization for which crystallization can be avoided and both the glass transition and the liquid-liquid phase transition are clearly separated, displays water-like anomalies as well as polyamorphism in both liquid and glassy states, providing a unique opportunity to study the interplay between the liquid-liquid phase transition and the glass transition. Our study on a simple model may be useful in understanding recent studies of polyamorphism in metallic glasses.

摘要

我们回顾了我们最近关于单原子系统中液态和玻璃态多态性的研究,该系统是一个具有吸引和排斥相互作用的双尺度球对称贾格拉模型。这种具有特定参数化的势,能够避免结晶,并且玻璃化转变和液-液相转变都能清晰分离,在液态和玻璃态中都表现出类似水的反常现象以及多态性,为研究液-液相转变和玻璃化转变之间的相互作用提供了独特的机会。我们对一个简单模型的研究可能有助于理解最近关于金属玻璃中多态性的研究。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e79/3100843/4bdc40e17792/ijms-11-05184f1.jpg

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