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聚[（乙腈-κN）-μ3-硫氰酸根合-κ(3)N:S:S-μ2-硫氰酸根合-κ(2)N:S-镉]

Poly[(aceto-nitrile-κN)-μ3-thio-cyanato-κ(3) N:S:S-μ2-thio-cyanato-κ(2) N:S-cadmium].

作者信息

Reinert Thorben, Jess Inke, Näther Christian

机构信息

Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24098 Kiel, Germany.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Jun 15;69(Pt 7):m398. doi: 10.1107/S1600536813015870. eCollection 2013.

DOI:10.1107/S1600536813015870
PMID:24046571
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3772428/
Abstract

The asymmetric unit of the title compound, [Cd(NCS)2(CH3CN)] n , consists of one Cd(II) cation, two thio-cyanate anions and one aceto-nitrile ligand, all in general positions. The Cd(II) cation is coordinated by three N atoms of two thio-cyanate anions and one aceto-nitrile ligand, as well as three S atoms of symmetry-related thio-cyanate anions within a slightly distorted octa-hedral coordination environment. The Cd(II) cations are linked by μ-1,3(N,S) and μ-1,1,3(S,S,N) thio-cyanate anions into layers that are located in the ab plane.

摘要

标题化合物[Cd(NCS)₂(CH₃CN)]ₙ的不对称单元由一个Cd(II)阳离子、两个硫氰酸根阴离子和一个乙腈配体组成，它们均处于一般位置。Cd(II)阳离子由两个硫氰酸根阴离子的三个N原子和一个乙腈配体配位，以及在稍微扭曲的八面体配位环境中与对称相关的硫氰酸根阴离子的三个S原子配位。Cd(II)阳离子通过μ-1,3(N,S)和μ-1,1,3(S,S,N)硫氰酸根阴离子连接成位于ab平面的层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b754/3772428/bfc4a9d5cdcf/e-69-0m398-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b754/3772428/2b84d45ec599/e-69-0m398-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b754/3772428/bfc4a9d5cdcf/e-69-0m398-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b754/3772428/2b84d45ec599/e-69-0m398-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b754/3772428/bfc4a9d5cdcf/e-69-0m398-fig2.jpg

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本文引用的文献

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A rational route to SCM materials based on a 1-D cobalt selenocyanato coordination polymer.基于一维钴硒氰酸配位聚合物的 SCM 材料的合理路线。
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Poly[bis-(acetonitrile-κN)di-μ-thio-cyanato-κN,S;κS,N-nickel(II)].聚[双（乙腈-κN）二-μ-硫氰酸根合-κN，S；κS，N-镍（II）]
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