从静态到动态：逃离腙基动态组合库中的动力学陷阱。
From static to dynamic: escaping kinetic traps in hydrazone-based dynamic combinatorial libraries.
机构信息
University Chemical Laboratory, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, United Kingdom.
出版信息
Chem Commun (Camb). 2011 Jul 14;47(26):7359-61. doi: 10.1039/c1cc12268a. Epub 2011 Jun 3.
PMID:21643569
Abstract
Thermodynamic control over kinetically-trapped mixtures of hydrazone-based macrocycles is achieved by addition of an aromatic monohydrazide to generate dynamic combinatorial libraries (DCLs) of linear and macrocyclic oligomers.
摘要
通过添加芳香单酰肼，实现了基于腙的大环化合物的动力学陷阱混合物的热力学控制，从而生成了线性和大环寡聚物的动态组合文库 (DCL)。
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