芳烃-烯烃光环加成反应。
The arene-alkene photocycloaddition.
机构信息
Department of Chemistry, University of Fribourg, Chemin du Musée 9, CH-1700 Fribourg, Switzerland.
出版信息
Beilstein J Org Chem. 2011;7:525-42. doi: 10.3762/bjoc.7.61. Epub 2011 Apr 28.
Abstract
In the presence of an alkene, three different modes of photocycloaddition with benzene derivatives can occur; the [2 + 2] or ortho, the [3 + 2] or meta, and the [4 + 2] or para photocycloaddition. This short review aims to demonstrate the synthetic power of these photocycloadditions.
摘要
在烯烃存在的情况下，苯衍生物可以发生三种不同模式的光环加成反应；[2 + 2]或邻位、[3 + 2]或间位和[4 + 2]或对位光环加成。本篇简短的综述旨在展示这些光环加成反应的合成威力。
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