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芳烃-烯烃光环加成反应。

The arene-alkene photocycloaddition.

机构信息

Department of Chemistry, University of Fribourg, Chemin du Musée 9, CH-1700 Fribourg, Switzerland.

出版信息

Beilstein J Org Chem. 2011;7:525-42. doi: 10.3762/bjoc.7.61. Epub 2011 Apr 28.

DOI:10.3762/bjoc.7.61
PMID:21647263
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3107530/
Abstract

In the presence of an alkene, three different modes of photocycloaddition with benzene derivatives can occur; the [2 + 2] or ortho, the [3 + 2] or meta, and the [4 + 2] or para photocycloaddition. This short review aims to demonstrate the synthetic power of these photocycloadditions.

摘要

在烯烃存在的情况下，苯衍生物可以发生三种不同模式的光环加成反应；[2 + 2]或邻位、[3 + 2]或间位和[4 + 2]或对位光环加成。本篇简短的综述旨在展示这些光环加成反应的合成威力。

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Chem Rev. 2008 Mar;108(3):1052-103. doi: 10.1021/cr0680336. Epub 2008 Feb 27.
8
From alpha-cedrene to crinipellin B and onward: 25 years of the alkene-arene meta-photocycloaddition reaction in natural product synthesis.从α-雪松烯到环柄菇素B及其他：天然产物合成中烯烃-芳烃间光环加成反应的25年历程。
Org Biomol Chem. 2006 Dec 21;4(24):4409-30. doi: 10.1039/b614011b. Epub 2006 Nov 3.
9
Carbon flatland: planar tetracoordinate carbon and fenestranes.碳平面世界：平面四配位碳与窗烷
Chem Rev. 2006 Dec;106(12):4787-808. doi: 10.1021/cr050545h.
10
Photochemistry of arenes--reloaded.芳烃的光化学——再探讨
Angew Chem Int Ed Engl. 2007;46(5):663-5. doi: 10.1002/anie.200603337.