Chappell David, Russell Andrew T
Department of Chemistry, University of Reading, Whiteknights, Reading, UK RG6 6AD.
Org Biomol Chem. 2006 Dec 21;4(24):4409-30. doi: 10.1039/b614011b. Epub 2006 Nov 3.
Wender and Howbert's remarkable synthesis of alpha-cedrene in 1981 brought the attention of the synthetic community to the alkene-arene meta-photocycloaddition reaction. Here we review the natural product syntheses that have been achieved, over the last 25 years, utilising this strategic level reaction.
1981年，温德（Wender）和豪伯特（Howbert）对α-雪松烯进行的卓越合成，将合成领域的注意力吸引到了烯烃-芳烃间位光环加成反应上。在此，我们回顾过去25年里利用这一关键反应所实现的天然产物合成。
