Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, PR China.
Chem Commun (Camb). 2011 Jul 21;47(27):7880-2. doi: 10.1039/c1cc12843d. Epub 2011 Jun 10.
The first ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acids is reported. Various aliphatic and aromatic aldehydes are transformed to the corresponding arylketones. A total of 31 examples with moderate to excellent yields are presented, together with the results of an initial mechanistic investigation.
首次报道了钌催化的醛与芳基硼酸的交叉偶联反应。各种脂肪族和芳香族醛都转化为相应的芳基酮。共呈现了 31 个具有中等至优异收率的实例，并进行了初步的机理研究。
