钌催化的醛与芳基硼酸交叉偶联合成芳基酮。
Synthesis of arylketones by ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acids.
机构信息
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, PR China.
出版信息
Chem Commun (Camb). 2011 Jul 21;47(27):7880-2. doi: 10.1039/c1cc12843d. Epub 2011 Jun 10.
PMID:21660337
Abstract
The first ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acids is reported. Various aliphatic and aromatic aldehydes are transformed to the corresponding arylketones. A total of 31 examples with moderate to excellent yields are presented, together with the results of an initial mechanistic investigation.
摘要
首次报道了钌催化的醛与芳基硼酸的交叉偶联反应。各种脂肪族和芳香族醛都转化为相应的芳基酮。共呈现了 31 个具有中等至优异收率的实例，并进行了初步的机理研究。
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