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本文引用的文献

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Sterically Controlled Pd-Catalyzed Chemoselective Ketone Synthesis via N-C Cleavage in Twisted Amides.扭曲酰胺中 N-C 键断裂的空间位阻控制钯催化酮的选择性合成。
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Electronic tuning of chiral diene ligands in iridium-catalyzed asymmetric 1,6-addition of arylboroxines to δ-aryl-α,β,γ,δ-unsaturated ketones.手性二烯配体在铱催化不对称芳基硼酸对δ-芳基-α,β,γ,δ-不饱和酮的 1,6-加成反应中的电子调谐。
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Ru/Me-BIPAM-catalyzed asymmetric addition of arylboronic acids to aliphatic aldehydes and α-ketoesters.Ru/Me-BIPAM 催化的芳基硼酸与脂肪醛和α-酮酯的不对称加成反应。
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Synthesis of arylketones by ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acids.钌催化的醛与芳基硼酸交叉偶联合成芳基酮。
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Sequential aldol condensation-transition metal-catalyzed addition reactions of aldehydes, methyl ketones, and arylboronic acids.醛、甲基酮和芳基硼酸的顺序羟醛缩合-过渡金属催化加成反应。
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Ir(COD)Cl]/亚磷酸三(2,4-二叔丁基苯基)催化芳基硼酸与醛的加成反应

Ir(COD)Cl]/Tris(2,4-di--butylphenyl)phosphite-Catalyzed Addition Reactions of Arylboronic Acids with Aldehydes.

作者信息

Liao Yuan-Xi, Dong Jie, Hu Qiao-Sheng

机构信息

Department of Chemistry, College of Staten Island of the City University of New York, Staten Island, New York, 10314 and the Ph.D. Program in Chemistry, the Graduate Center of the City University of New York, New York, NY 10016, United States.

出版信息

Tetrahedron Lett. 2018 Apr 18;59(16):1548-1550. doi: 10.1016/j.tetlet.2018.02.071. Epub 2018 Mar 2.

DOI:10.1016/j.tetlet.2018.02.071
PMID:30333670
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6186456/
Abstract

[Ir(COD)Cl]/tris(2,4-di--butylphenyl)phosphite-catalyzed addition reactions of arylboronic acids with aldehydes were described. The Ir(I) catalyst, generated from [Ir(COD)Cl] and tris(2,4-di--butylphenyl)phosphite, was an efficient catalyst system for the addition reactions of a variety of arylboronic acids with aromatic and aliphatic aldehydes. The easy availability of the catalyst and good yields make these reactions potentially useful in organic synthesis.

摘要

描述了[Ir(COD)Cl]/亚磷酸三(2,4-二叔丁基苯基)催化的芳基硼酸与醛的加成反应。由[Ir(COD)Cl]和亚磷酸三(2,4-二叔丁基苯基)生成的Ir(I)催化剂是用于多种芳基硼酸与芳香族和脂肪族醛加成反应的高效催化体系。该催化剂易于获得且产率良好，使得这些反应在有机合成中具有潜在的实用性。