受阻路易斯酸碱对与共轭烯炔酮的反应——碳-碳三键的选择性氢化 - Suppr

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Reaction of frustrated Lewis pairs with conjugated ynones-selective hydrogenation of the carbon-carbon triple bond.

作者信息

Xu Bao-Hua, Kehr Gerald, Fröhlich Roland, Wibbeling Birgit, Schirmer Birgitta, Grimme Stefan, Erker Gerhard

机构信息

Organisch-Chemisches Institut der Universität Münster, Münster, Germany.

出版信息

Angew Chem Int Ed Engl. 2011 Jul 25;50(31):7183-6. doi: 10.1002/anie.201101051. Epub 2011 Jun 16.

DOI:10.1002/anie.201101051

PMID:21681875

Abstract

摘要

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Reaction of frustrated Lewis pairs with conjugated ynones-selective hydrogenation of the carbon-carbon triple bond.

作者信息

Xu Bao-Hua, Kehr Gerald, Fröhlich Roland, Wibbeling Birgit, Schirmer Birgitta, Grimme Stefan, Erker Gerhard

机构信息

Organisch-Chemisches Institut der Universität Münster, Münster, Germany.

出版信息

Angew Chem Int Ed Engl. 2011 Jul 25;50(31):7183-6. doi: 10.1002/anie.201101051. Epub 2011 Jun 16.

DOI:10.1002/anie.201101051

PMID:21681875

Abstract

摘要

相似文献

Reaction of frustrated Lewis pairs with conjugated ynones-selective hydrogenation of the carbon-carbon triple bond.

Angew Chem Int Ed Engl. 2011 Jul 25;50(31):7183-6. doi: 10.1002/anie.201101051. Epub 2011 Jun 16.

Frustrated Lewis pairs: metal-free hydrogen activation and more.

Angew Chem Int Ed Engl. 2010;49(1):46-76. doi: 10.1002/anie.200903708.

Mechanistic insight on the hydrogenation of conjugated alkenes with h(2) catalyzed by early main-group metal catalysts.

Inorg Chem. 2010 Apr 5;49(7):3361-9. doi: 10.1021/ic902418v.

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Chem Asian J. 2012 Jun;7(6):1347-56. doi: 10.1002/asia.201100960. Epub 2012 Mar 7.

Activation of the P-H bond by a frustrated Lewis pair and its application in catalytic Z-selective hydrophosphonylation of terminal ynones.

Chem Commun (Camb). 2017 Oct 3;53(79):10890-10893. doi: 10.1039/c7cc05028c.

Catalytic hydrogenation with frustrated Lewis pairs: selectivity achieved by size-exclusion design of Lewis acids.

Chemistry. 2012 Jan 9;18(2):574-85. doi: 10.1002/chem.201102438. Epub 2011 Dec 12.

Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis.

Dalton Trans. 2009 May 7(17):3129-36. doi: 10.1039/b819621d. Epub 2009 Feb 18.

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J Am Chem Soc. 2008 Aug 6;130(31):10263-73. doi: 10.1021/ja803509y. Epub 2008 Jul 10.

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J Am Chem Soc. 2009 Aug 5;131(30):10701-10. doi: 10.1021/ja903878z.

Metal-free catalytic hydrogenation of polar substrates by frustrated Lewis pairs.

Inorg Chem. 2011 Dec 19;50(24):12338-48. doi: 10.1021/ic200663v. Epub 2011 May 2.

引用本文的文献

Catalytic, -Selective, Semi-Hydrogenation of Alkynes with a Zinc-Anilide Complex.

J Am Chem Soc. 2023 Apr 5;145(13):7667-7674. doi: 10.1021/jacs.3c02301. Epub 2023 Mar 27.

Triphenylborane in Metal-Free Catalysis.

Molecules. 2023 Jan 31;28(3):1340. doi: 10.3390/molecules28031340.

Molybdenum(VI) Bis(imido) Complexes: From Frustrated Lewis Pairs to Weakly Coordinating Cations.

Chemistry. 2022 Oct 4;28(55):e202201867. doi: 10.1002/chem.202201867. Epub 2022 Aug 3.

Reaction of FcC[triple bond, length as m-dash]CC(O)R (Fc = ferrocenyl) with Ru(CO) leading to unexpected nitro-group reduced ruthenoles and 1,2-CO-inserted triruthenium clusters.

RSC Adv. 2018 Jul 16;8(45):25268-25276. doi: 10.1039/c8ra04548h.

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Chemistry. 2022 Feb 16;28(9):e202104254. doi: 10.1002/chem.202104254. Epub 2021 Dec 28.

N-Geminal P/Al Lewis Pair-Alkyne Dipolar Cycloaddition to the Zwitterionic CPNAl-Heterocyclopentene.

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Nat Chem. 2013 Aug;5(8):718-23. doi: 10.1038/nchem.1693. Epub 2013 Jul 7.

Haloboration of internal alkynes with boronium and borenium cations as a route to tetrasubstituted alkenes.

Angew Chem Int Ed Engl. 2013 Jul 15;52(29):7518-22. doi: 10.1002/anie.201302609. Epub 2013 Jun 5.