三氟甲基酮与 Aryne 的三种反应模式：C-C 键断裂、[2+2]环加成和 O-芳基化。
Aryne reaction with trifluoromethyl ketones in three modes: C-C bond cleavage, [2+2] cycloaddition and O-arylation.
机构信息
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan.
出版信息
Chem Commun (Camb). 2011 Aug 14;47(30):8664-6. doi: 10.1039/c1cc12820e. Epub 2011 Jun 27.
PMID:21706101
Abstract
Trifluoromethyl ketones were found to be coupled with arynes in three modes depending upon their substitution patterns, namely C-C bond cleavage, [2+2] cycloaddition and O-arylation.
摘要
三氟甲基酮根据取代模式与芳基炔发生偶联反应，有三种方式，分别为 C-C 键断裂、[2+2]环加成和 O-芳基化。
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