Chiper Manuela, Hoogenboom Richard, Schubert Ulrich S
Laboratory of Macromolecular Chemistry and Nanoscience, Eindhoven University of Technology, Eindhoven, The Netherlands; Dutch Polymer Institute (DPI), P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
Macromol Rapid Commun. 2009 Apr 20;30(8):565-78. doi: 10.1002/marc.200800625. Epub 2009 Feb 18.
Metallo-supramolecular chemistry offers possibilities for the construction of stimuli-responsive polymeric materials where the environment can have a large impact on the reversibility and strength of interactions between the individual components. The potential of manipulating the strength of the intermolecular non-covalent bonds can result in impressive modifications of the metallo-supramolecular structure and, subsequently, produces changes in the properties of the designed material. The present feature article provides an overview on recent developments in the field of metallo-polymerization of chelating terpyridyl and analogues ligands. Synthetic strategies are described followed by a discussion regarding the characterization and the application of the reviewed metallo-supramolecular structures, mainly based on terpyridines.
金属超分子化学为构建刺激响应性聚合物材料提供了可能性，在这种材料中，环境会对各个组分之间相互作用的可逆性和强度产生重大影响。调控分子间非共价键强度的潜力能够显著改变金属超分子结构，进而使所设计材料的性能发生变化。本篇专题文章概述了螯合三联吡啶及其类似物配体的金属聚合领域的最新进展。文中描述了合成策略，随后讨论了所综述的主要基于三联吡啶的金属超分子结构的表征及应用。
