Yuan Ming, Wang Feng, Tian Yu-Kui
CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China Hefei 230026 P. R. China.
Clinic Medical College of Anhui Medical University Hefei 230012 P. R. China.
RSC Adv. 2018 Dec 5;8(71):40794-40797. doi: 10.1039/c8ra08615j. eCollection 2018 Dec 4.
Metallo-supramolecular polymers with the incorporation of benzothiadiazole-substituted organoplatinum moiety have been successfully constructed. The designed monomer displays intense fluorescence signals, which are severely quenched upon the supramolecular polymerization process. On-off switching of fluorescence can be further exploited for data security materials in response to the chemical stimuli. Accordingly, the resulting supramolecular polymers can be regarded as a novel and efficient candidate toward information processing applications.
已成功构建了含有苯并噻二唑取代有机铂部分的金属超分子聚合物。所设计的单体显示出强烈的荧光信号，在超分子聚合过程中这些信号会被严重淬灭。荧光的开-关切换可进一步用于响应化学刺激的数据安全材料。因此，所得的超分子聚合物可被视为信息处理应用的一种新型高效候选物。
