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对异质CaCu3Ti4O12薄膜的扫描探针显微镜研究

Scanning Probe Microscopy on heterogeneous CaCu3Ti4O12 thin films.

作者信息

Fiorenza Patrick, Lo Nigro Raffaella, Raineri Vito

机构信息

Istituto per la Microelettronica e Microsistemi (IMM), Consiglio Nazionale delle Ricerche, Strada VIII, 5; 95121 Catania, Italy.

出版信息

Nanoscale Res Lett. 2011 Feb 4;6(1):118. doi: 10.1186/1556-276X-6-118.

DOI:10.1186/1556-276X-6-118
PMID:21711646
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3211163/
Abstract

The conductive atomic force microscopy provided a local characterization of the dielectric heterogeneities in CaCu3Ti4O12 (CCTO) thin films deposited by MOCVD on IrO2 bottom electrode. In particular, both techniques have been employed to clarify the role of the inter- and sub-granular features in terms of conductive and insulating regions. The microstructure and the dielectric properties of CCTO thin films have been studied and the evidence of internal barriers in CCTO thin films has been provided. The role of internal barriers and the possible explanation for the extrinsic origin of the giant dielectric response in CCTO has been evaluated.

摘要

导电原子力显微镜对通过金属有机化学气相沉积(MOCVD)法沉积在二氧化铱底部电极上的CaCu3Ti4O12(CCTO)薄膜中的介电不均匀性进行了局部表征。特别是,这两种技术都被用于阐明晶间和亚颗粒特征在导电和绝缘区域方面的作用。研究了CCTO薄膜的微观结构和介电性能,并提供了CCTO薄膜内部势垒的证据。评估了内部势垒的作用以及对CCTO中巨大介电响应的非本征起源的可能解释。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/572e/3211163/e3a924277550/1556-276X-6-118-3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/572e/3211163/4e3c11120e41/1556-276X-6-118-1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/572e/3211163/b82322aa6c98/1556-276X-6-118-2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/572e/3211163/e3a924277550/1556-276X-6-118-3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/572e/3211163/4e3c11120e41/1556-276X-6-118-1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/572e/3211163/b82322aa6c98/1556-276X-6-118-2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/572e/3211163/e3a924277550/1556-276X-6-118-3.jpg

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本文引用的文献

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Calcium copper-titanate thin film growth: tailoring of the operational conditions through nanocharacterization and substrate nature effects.钛酸钙铜薄膜生长:通过纳米表征和衬底性质效应调整操作条件
J Phys Chem B. 2006 Sep 7;110(35):17460-7. doi: 10.1021/jp062559c.
2
Recent advances in characterization of CaCu3Ti4O12 thin films by spectroscopic ellipsometric metrology.利用光谱椭偏测量法表征CaCu3Ti4O12薄膜的最新进展。
J Am Chem Soc. 2005 Oct 12;127(40):13772-3. doi: 10.1021/ja0541229.
3
Strong nonlinear current-voltage behaviour in perovskite-derivative calcium copper titanate.
钙钛矿衍生物钛酸钙铜中的强非线性电流-电压行为
Nat Mater. 2004 Nov;3(11):774-8. doi: 10.1038/nmat1238. Epub 2004 Oct 10.
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Optical response of high-dielectric-constant perovskite-related oxide.高介电常数钙钛矿相关氧化物的光学响应
Science. 2001 Jul 27;293(5530):673-6. doi: 10.1126/science.1061655.