Laboratory of Organic and Macromolecular Chemistry, Friedrich-Schiller-University Jena, Germany.
Macromol Rapid Commun. 2011 Sep 15;32(18):1484-9. doi: 10.1002/marc.201100271. Epub 2011 Jul 13.
The bulk polymerization of 2-(dec-9-enyl)-2-oxazoline (DecEnOx), a fatty acid-based monomer for the cationic ring-opening polymerization, is reported. Furthermore, under optimal conditions, namely microwave heating at 100 °C, the bulk copolymerization with 2-ethyl-2-oxazoline yielded well-defined copolymers. Due to its pendant alkene groups DecEnOx-based polymers possess the potential to be modified in efficient thiol-ene reactions. The functionalization with thiols, e.g., dodecanethiol and 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glycopyranose in "green" solvents is demonstrated.
报道了一种基于脂肪酸的单体 2-(癸-9-烯基)-2-恶唑啉（DecEnOx）的本体聚合，该单体可用于阳离子开环聚合。此外，在最佳条件下，即在 100°C 的微波加热下，与 2-乙基-2-恶唑啉进行本体共聚可得到具有明确结构的共聚物。由于其侧链烯基，基于 DecEnOx 的聚合物具有通过有效的硫醇-烯反应进行修饰的潜力。在“绿色”溶剂中用硫醇（例如十二硫醇和 2,3,4,6-四-O-乙酰基-1-硫代-β-D-吡喃葡萄糖苷）对其进行功能化得到了证明。
