Luef Klaus P, Hoogenboom Richard, Schubert Ulrich S, Wiesbrock Frank
Polymer Competence Center Leoben GmbH, Roseggerstrasse 12, 8700 Leoben, Austria; Graz University of Technology, Institute for Chemistry and Technology of Materials, NAWI Graz, Stremayrgasse 9, 8010 Graz, Austria.
Supramolecular Chemistry Group, Department of Organic and Macromolecular Chemistry, Ghent University, Krijgslaan 281 S4, 9000 Ghent, Belgium.
Adv Polym Sci. 2015 Oct 28;274:183-208. doi: 10.1007/12_2015_340.
Unlike any other polymer class, the (co-)poly(2-oxazoline)s have tremendously benefited from the introduction of microwave reactors into chemical laboratories. This review focuses on the research activities in the area of (co-)poly(2-oxazoline)s prepared by microwave-assisted syntheses and, correspondingly, summarizes the current-state-of the-art of the microwave-assisted synthesis of 2-oxazoline monomers and the microwave-assisted ring-opening (co-)polymerization of 2-oxazolines as well as prominent examples of post-polymerization modification of (co-)poly(2-oxazoline)s. Special attention is attributed to the kinetic analysis of the microwave-assisted polymerization of 2-oxazolines and the discussion of non-thermal microwave effects.
与其他任何聚合物类别不同，（共）聚（2-恶唑啉）极大地受益于微波反应器引入化学实验室。本综述聚焦于通过微波辅助合成制备（共）聚（2-恶唑啉）领域的研究活动，并相应总结了2-恶唑啉单体微波辅助合成、2-恶唑啉的微波辅助开环（共）聚合以及（共）聚（2-恶唑啉）后聚合改性的突出实例的当前技术水平。特别关注2-恶唑啉微波辅助聚合的动力学分析以及非热微波效应的讨论。
