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链状聚[[四水合-[反式-1,2-双-(4-吡啶基)乙烯-κN:N']镍(II)]二硝酸盐]

catena-Poly[[tetra-aqua-[trans-1,2-bis-(4-pyrid-yl)ethene-κN:N']nickel(II)] dinitrate].

作者信息

Hyun Min Young, Kim Pan-Gi, Kim Cheal, Kim Youngmee

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m390. doi: 10.1107/S1600536811007021. Epub 2011 Mar 2.

DOI:10.1107/S1600536811007021
PMID:21753926
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3100072/
Abstract

In the title compound, {Ni(C(12)H(10)N(2))(H(2)O)(4)(2)}(n), the Ni(II) ion, lying on a crystallographic inversion center, has a distorted octa-hedral coordination sphere comprising four water ligands and two N-atom donors from the trans-related 1,2-bis-(4-pyrid-yl)ethene ligands, which also have crystallographic inversion symmetry. These ligands bridge the Ni(II) complex units, forming chains extending along the [110] and [[Formula: see text]10] directions. The nitrate counter-anions stabilize the crystal structure through water-nitrate O-H⋯O hydrogen bonds.

摘要

在标题化合物{Ni(C₁₂H₁₀N₂)(H₂O)₄₂}ₙ中，位于晶体学反演中心的Ni(II)离子具有扭曲的八面体配位环境，由四个水配体和来自反式相关的1,2-双(4-吡啶基)乙烯配体的两个N原子供体组成，这些配体也具有晶体学反演对称性。这些配体桥连Ni(II)络合物单元，形成沿[110]和[[化学式：见原文]10]方向延伸的链。硝酸根抗衡阴离子通过水-硝酸根O-H⋯O氢键稳定晶体结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b6e4/3100072/0d5b7245b7c7/e-67-0m390-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b6e4/3100072/0d5b7245b7c7/e-67-0m390-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b6e4/3100072/0d5b7245b7c7/e-67-0m390-fig1.jpg

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