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聚[[双-[μ-1,2-双-(4-吡啶基)乙烯]双-(三氯乙酸根)-镉(II)]]一水合物

Poly[[bis-[μ-1,2-bis-(4-pyrid-yl)ethene]bis-(trichloro-acetato)-cadmium(II)] monohydrate].

作者信息

Kim Jin Hoon, Kim Cheal, Kim Youngmee

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 4;67(Pt 1):m3-4. doi: 10.1107/S1600536810049457.

DOI:10.1107/S1600536810049457
PMID:21522553
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3050134/
Abstract

In the crystal structure of the title compound, {[Cd(C(2)Cl(3)O(2))(2)(C(12)H(10)N(2))(2)]·H(2)O}(n), the Cd(II) ion lies on a twofold rotation axis and 1,2-bis-(4-pyrid-yl)ethene ligands bridge symmetry-related Cd(II) ions, forming a two-dimensional structure. Two trichloro-acetate ligands complete the coordination around the Cd(II )ion, forming a distorted octa-hedral environment. In the crystal, solvent water mol-ecules, which also lie on twofold rotation axes, form inter-molecular O-H⋯O hydrogen bonds, which connect the two-dimensional structure into a three-dimensional network. The crystal studied was an inversion twin, the refined ratio of twin components being 0.75 (4):0.25 (4).

摘要

在标题化合物{[Cd(C₂Cl₃O₂)₂(C₁₂H₁₀N₂)₂]·H₂O}ₙ的晶体结构中，Cd(II)离子位于二重旋转轴上，1,2-双（4-吡啶基）乙烯配体桥连对称相关的Cd(II)离子，形成二维结构。两个三氯乙酸根配体完成了Cd(II)离子周围的配位，形成扭曲的八面体环境。在晶体中，同样位于二重旋转轴上的溶剂水分子形成分子间O-H⋯O氢键，将二维结构连接成三维网络。所研究的晶体是一个倒转孪晶，孪晶组分的精修比例为0.75 (4):0.25 (4)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1dd6/3050134/da70a35773de/e-67-000m3-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1dd6/3050134/c940067a8d85/e-67-000m3-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1dd6/3050134/da70a35773de/e-67-000m3-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1dd6/3050134/c940067a8d85/e-67-000m3-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1dd6/3050134/da70a35773de/e-67-000m3-fig2.jpg

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本文引用的文献

1
Interpenetrating Nets: Ordered, Periodic Entanglement.互穿网络：有序、周期性缠结。
Angew Chem Int Ed Engl. 1998 Jun 19;37(11):1460-1494. doi: 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO;2-Z.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Synthesis, structure and heterogeneous catalytic activities of Cu-containing polymeric compounds: anion effect and comparison of homogeneous vs. heterogeneous catalytic activity.
Bis(μ-2-carboxymethyl-2-hydroxy-butane-dioato)bis-[diaqua-manganese(II)]-1,2-bis-(pyridin-4-yl)ethane-water (1/1/2).
双（μ-2-羧甲基-2-羟基丁二酸根）双-[二水合锰（II）]-1,2-双（吡啶-4-基）乙烷-水（1/1/2）
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1116-7. doi: 10.1107/S1600536812032771. Epub 2012 Jul 25.
4
Bis(methanol-κO)bis-(quinoline-2-carboxyl-ato-κN,O)nickel(II).双（甲醇-κO）双（喹啉-2-羧酸根-κN，O）镍（II）
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1511. doi: 10.1107/S1600536811041134. Epub 2011 Oct 12.
5
catena-Poly[[bis-(2,4-dichloro-benzoato)bis-(methanol-κO)cobalt(II)]-μ-4,4'-bipyridine-κN:N'].链状聚[[双-(2,4-二氯苯甲酸根)双-(甲醇-κO)钴(II)]-μ-4,4'-联吡啶-κN:N']
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1705. doi: 10.1107/S1600536811046149. Epub 2011 Nov 9.
6
catena-Poly[[tetra-aqua-[trans-1,2-bis-(4-pyrid-yl)ethene-κN:N']nickel(II)] dinitrate].链状聚[[四水合-[反式-1,2-双-(4-吡啶基)乙烯-κN:N']镍(II)]二硝酸盐]
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m390. doi: 10.1107/S1600536811007021. Epub 2011 Mar 2.
含铜聚合物化合物的合成、结构及多相催化活性：阴离子效应及均相与多相催化活性比较
Dalton Trans. 2004 Sep 7(17):2697-701. doi: 10.1039/B406877G. Epub 2004 Aug 5.
4
Functional porous coordination polymers.功能性多孔配位聚合物
Angew Chem Int Ed Engl. 2004 Apr 26;43(18):2334-75. doi: 10.1002/anie.200300610.
5
Metal-bridged polymers as insoluble multicomponent asymmetric catalysts with high enantiocontrol: an approach for the immobilization of catalysts without using any support.金属桥连聚合物作为具有高对映选择性控制的不溶性多组分不对称催化剂：一种无需使用任何载体的催化剂固定化方法。
Angew Chem Int Ed Engl. 2003 Dec 1;42(46):5711-4. doi: 10.1002/anie.200352354.
6
Crystal engineering of NLO materials based on metal--organic coordination networks.基于金属有机配位网络的非线性光学材料的晶体工程
Acc Chem Res. 2002 Jul;35(7):511-22. doi: 10.1021/ar0001012.
7
From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids.从分子到晶体工程：网络固体中的超分子异构现象和多晶型现象
Chem Rev. 2001 Jun;101(6):1629-58. doi: 10.1021/cr9900432.
8
Modular chemistry: secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks.
Acc Chem Res. 2001 Apr;34(4):319-30. doi: 10.1021/ar000034b.