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链状聚[[双-(2,4-二氯苯甲酸根)双-(甲醇-κO)钴(II)]-μ-4,4'-联吡啶-κN:N']

catena-Poly[[bis-(2,4-dichloro-benzoato)bis-(methanol-κO)cobalt(II)]-μ-4,4'-bipyridine-κN:N'].

作者信息

Hyun Min Young, Kim Pan-Gi, Kim Cheal, Kim Youngmee

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1705. doi: 10.1107/S1600536811046149. Epub 2011 Nov 9.

DOI:10.1107/S1600536811046149
PMID:22199519
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3238628/
Abstract

In the title compound, Co(C(7)H(3)Cl(2)O(2))(2)(C(10)H(8)N(2))(CH(3)OH)(2), the Co(II) ion lies on a twofold rotation axis and is in a slightly distorted octa-hedral CdO(4)N(2) environment, formed by two O atoms from monodentate dichloro-benzoate ligands, two O atoms from methanol ligands, and two N atoms from trans-related 4,4'-bipyridine ligands. The bipyridine ligands also lies on a twofold rotation axis and bridge the Co(II) ions, forming chains extending along [010]. An intra-chain O-H⋯O hydrogen bond is observed.

摘要

在标题化合物[Co(C₇H₃Cl₂O₂)₂(C₁₀H₈N₂)(CH₃OH)₂]ₙ中，Co(II)离子位于一个二重旋转轴上，处于一个略有扭曲的八面体CdO₄N₂环境中，该环境由单齿二氯苯甲酸酯配体的两个O原子、甲醇配体的两个O原子以及反式相关的4,4'-联吡啶配体的两个N原子构成。联吡啶配体也位于一个二重旋转轴上，并桥连Co(II)离子，形成沿[010]方向延伸的链。观察到链内存在O-H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9c22/3238628/6a8521e61690/e-67-m1705-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9c22/3238628/6a8521e61690/e-67-m1705-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9c22/3238628/6a8521e61690/e-67-m1705-fig1.jpg

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本文引用的文献

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A MnII4 cubane and a novel MnII10MnIII4 cluster from the use of di-2-pyridyl ketone in manganese acetate chemistry.在醋酸锰化学中使用二 - 2 - 吡啶基酮得到的一个锰（II）4立方烷和一个新型锰（II）10锰（III）4簇合物。
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