六氯锡（IV）酸双（3-羟甲基苯胺鎓）
Bis(3-hy-droxy-methyl-anilinium) hexa-chloridostannate(IV).
作者信息
Bouacida Sofiane, Kechout Habiba, Belhouas Ratiba, Merazig Hocine, Roisnel Thierry
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m395. doi: 10.1107/S1600536811007252. Epub 2011 Mar 2.
In the title compound, (C(7)H(10)NO)(2)[SnCl(6)], the Sn(IV) atom, located on an inversion center, exists in an octa-hedral coordination environment. The crystal structure exhibits alternating organic and inorganic layers parallel to ([Formula: see text]01). The cations and anions are linked via inter-molecular N-H⋯O, N-H⋯Cl and O-H⋯Cl hydrogen bonds. Additional stabilization is provided by π-π stacking inter-actions between the benzene rings of the cations [centroid-centroid distances = 3.6962 (15) and 3.9340 (15) Å].
在标题化合物（C₇H₁₀NO）₂[SnCl₆]中，位于对称中心的Sn(IV)原子处于八面体配位环境中。晶体结构呈现出平行于（[化学式：见原文]01）的交替有机层和无机层。阳离子和阴离子通过分子间的N-H⋯O、N-H⋯Cl和O-H⋯Cl氢键相连。阳离子苯环之间的π-π堆积相互作用[质心-质心距离 = 3.6962 (15) 和3.9340 (15) Å]提供了额外的稳定性。
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