Rademeyer Melanie
School of Pure and Applied Chemistry, University of Natal, Durban, 4041, South Africa.
Acta Crystallogr C. 2004 Feb;60(Pt 2):m55-6. doi: 10.1107/S0108270103028270. Epub 2004 Jan 10.
The crystal structure of bis(benzylammonium) hexachlorotin(IV), (C(7)H(7)NH(3))(2)[SnCl(6)], exhibits ionic layers separated by hydrocarbon layers. The hydrocarbon layer contains two crystallographically inequivalent benzyl groups and aromatic pi-pi stacking interactions are observed in this layer. In the inorganic layer, the ammonium groups interact with isolated tilted SnCl(6) octahedra through normal, bifurcated and trifurcated N-H.Cl hydrogen bonds.
双（苄基铵）六氯锡（IV），即（C₇H₇NH₃）₂[SnCl₆]的晶体结构显示，离子层被烃层隔开。烃层包含两个晶体学上不等价的苄基，并且在该层中观察到芳香π-π堆积相互作用。在无机层中，铵基团通过正常、分叉和三叉N-H···Cl氢键与孤立的倾斜[SnCl₆]²⁻八面体相互作用。
