[1,2-双（吡啶-2-基甲氧基）苯-κN，O，O'，N']二氯化铜（II）
[1,2-Bis(pyridin-2-ylmeth-oxy)benzene-κN,O,O',N']dichloridocopper(II).
作者信息
Huang Nan-Nan, Zhang Shuang, Liu Ying, Hou Guang-Feng, Gao Jin-Sheng
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m596. doi: 10.1107/S160053681101333X. Epub 2011 Apr 16.
Abstract
In the title compound, [CuCl(2)(C(18)H(16)N(2)O(2))], the Cu(II) atom lies on a twofold axis and is six-coordinated in a distorted octa-hedral environment defined by two N and two O atoms from the ligand and by two Cl atoms. In the crystal, π-π inter-actions [centroid-centroid distance = 3.838 (1) Å] and C-H⋯Cl hydrogen bonds link adjacent mol-ecules into a chain structure along [101].
摘要
在标题化合物[CuCl₂(C₁₈H₁₆N₂O₂)]中，Cu(II)原子位于二重轴上，在由来自配体的两个N原子、两个O原子以及两个Cl原子所定义的扭曲八面体环境中呈六配位。在晶体中，π-π相互作用[质心-质心距离 = 3.838 (1) Å]和C-H⋯Cl氢键将相邻分子沿[101]连接成链状结构。
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