（5,5'-二甲基-2,2'-联吡啶）-碘代-三甲基-铂（IV）
(5,5'-Dimethyl-2,2'-bipyridine)-iodido-trimethyl-platinum(IV).
作者信息
Lundvall Fredrik, Wragg David Stephen, Tilset Mats
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m617-8. doi: 10.1107/S1600536811014085. Epub 2011 Apr 22.
In the title compound, [Pt(CH(3))(3)I(C(12)H(12)N(2))], the Pt(IV) atom is six-coordinated in a slightly distorted octa-hedral configuration with one CH(3) group and the I atom forming a near perpendicular axis relative to the square plane formed by the bipyridine ligand and the two remaining CH(3) groups. The CH(3) group trans to the I atom has a slightly elongated bond to Pt compared to the other CH(3) groups, indicating a difference in trans influence between iodine and the bipyridine ligand.
在标题化合物[Pt(CH₃)₃I(C₁₂H₁₂N₂)]中，Pt(IV)原子以略微扭曲的八面体构型进行六配位，其中一个CH₃基团和I原子相对于由联吡啶配体以及另外两个CH₃基团形成的平面构成近乎垂直的轴。与I原子相对的CH₃基团与Pt的键长相比其他CH₃基团略有伸长，这表明碘和联吡啶配体之间的反位影响存在差异。
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