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四氯（4,4'-二甲基-2,2'-联吡啶-κN,N'）铂（IV）

Tetra-chlorido(4,4'-dimethyl-2,2'-bipyridine-κN,N')platinum(IV).

作者信息

Hojjat Kashani Leila, Amani Vahid, Yousefi Mohammad, Khavasi Hamid Reza

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 13;64(Pt 7):m905-6. doi: 10.1107/S1600536808016796.

DOI:10.1107/S1600536808016796
PMID:21202769
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961848/
Abstract

The asymmetric unit of the title compound, [PtCl(4)(C(12)H(12)N(2))], contains one half-mol-ecule; a twofold rotation axis passes through the Pt atom and the mid-point of the C-C bond linking the two rings. The Pt(IV) atom is six-coordinated in an octa-hedral configuration by two N atoms of the 4,4'-dimethyl-2,2'-bipyridine ligand and four terminal Cl atoms. In the crystal structure, there are weak π-π inter-actions between pyridine rings, with a centroid-centroid distance of 4.365 (3) Å.

摘要

标题化合物[PtCl₄(C₁₂H₁₂N₂)]的不对称单元包含半个分子；一个二重旋转轴穿过铂原子以及连接两个环的碳 - 碳键的中点。Pt(IV)原子通过4,4'-二甲基-2,2'-联吡啶配体的两个N原子和四个末端Cl原子以八面体构型进行六配位。在晶体结构中，吡啶环之间存在弱的π - π相互作用，质心 - 质心距离为4.365 (3) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c479/2961848/f2b579811385/e-64-0m905-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c479/2961848/f2b579811385/e-64-0m905-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c479/2961848/f2b579811385/e-64-0m905-fig1.jpg

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