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二茂铁基(甲基)二苯基硅烷

Ferrocen-yl(meth-yl)diphenyl-silane.

作者信息

Liu Yu-Peng, Li Zong-Qi, Tan Yong-Xia, Zhang Zhi-Jie

机构信息

Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m636. doi: 10.1107/S1600536811014796. Epub 2011 Apr 29.

Abstract

In the title mol-ecule, [Fe(C(5)H(5))(C(18)H(17)Si)], the distances of the Fe atom from the centroids of the unsubstituted and substituted cyclo-penta-dienyl (Cp) rings are 1.651 (1) and 1.646 (1) Å, respectively. The dihedral angle between the two Cp rings is 3.20 (17)°. The crystal packing is mainly stabilized by van der Waals forces.

摘要

在标题分子[Fe(C₅H₅)(C₁₈H₁₇Si)]中,铁原子与未取代和取代的环戊二烯基(Cp)环质心的距离分别为1.651(1)Å和1.646(1)Å。两个Cp环之间的二面角为3.20(17)°。晶体堆积主要通过范德华力得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f6f/3089205/042ba8826967/e-67-0m636-fig1.jpg

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