Wang Ying-Chun
College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m180. doi: 10.1107/S1600536812001766. Epub 2012 Jan 21.
The asymmetric unit of the title complex, [Fe(C(5)H(5))(C(11)H(17)N)]ClO(4), contains two independent all-yl(ferro-cenyl-meth-yl)dimethyl-ammonium cations and two ClO(4) (-) anions. The anions are disordered each over two sets of sites, with an occupancy ratio of 0.617 (6):0.383 (6). The distances from the Fe atoms to the centroids of the unsubstituted and substituted cyclo-penta-dienyl (Cp) rings are 1.645 (1)/1.657 (1) and 1.644 (1)/1.647 (1) Å. The dihedral angles between the two Cp rings are 2.49 (3) and 1.45 (4)° in the two ferrocenyl groups of the cations.
标题配合物[Fe(C₅H₅)(C₁₁H₁₇N)]ClO₄的不对称单元包含两个独立的烯丙基（二茂铁基甲基）二甲基铵阳离子和两个ClO₄⁻阴离子。阴离子在两组位置上无序分布，占有率为0.617 (6):0.383 (6)。铁原子到未取代和取代环戊二烯基（Cp）环质心的距离分别为1.645 (1)/1.657 (1) 和1.644 (1)/1.647 (1) Å。阳离子的两个二茂铁基团中两个Cp环之间的二面角分别为2.49 (3) 和1.45 (4)°。
