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高氯酸（二茂铁基甲基）三甲基铵

(Ferrocenylmeth-yl)trimethyl-ammonium perchlorate.

作者信息

Wang Ying-Chun

机构信息

College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m197. doi: 10.1107/S1600536812002176. Epub 2012 Jan 21.

DOI:10.1107/S1600536812002176
PMID:22346865
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3274918/
Abstract

The asymmetric unit of the title complex, [Fe(C(5)H(5))(C(9)H(15)N)]ClO(4), contains one discrete (ferrocenylmeth-yl)trimethyl-ammonium cation and one perchlorate anion. The anion is disordered over two sets of sites, with refined occupancies of 0.776 (8) and 0.224 (8). The distances from the Fe atom to the centroids of the unsubstituted and substituted cyclo-penta-dienyl (Cp) rings are 1.650 (1) and 1.640 (1) Å, respectively. The Cp rings form a dihedral angle of 2.66 (3)°.

摘要

标题配合物[Fe(C₅H₅)(C₉H₁₅N)]ClO₄的不对称单元包含一个离散的（二茂铁基甲基）三甲基铵阳离子和一个高氯酸根阴离子。阴离子在两组位置上无序，精修占有率分别为0.776 (8)和0.224 (8)。铁原子到未取代和取代的环戊二烯基（Cp）环质心的距离分别为1.650 (1) Å和1.640 (1) Å。Cp环形成的二面角为2.66 (3)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3d00/3274918/a114aca09a75/e-68-0m197-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3d00/3274918/a114aca09a75/e-68-0m197-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3d00/3274918/a114aca09a75/e-68-0m197-fig1.jpg

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